It really could not get more simple than this, but all too many people insist on confusing themselves on this point by listening to bad advice peddled by people who supposedly have closed this deal or that deal or 50 deals on their word.
So let's sum things up: The LOI and similar documentary terms, are non standard, confusing, and lead to ambiguity. Documentary ambiguity is referred to in trade law as a condition "The Battle of the Forms" in which confusion from contradictory and ambiguous forms and documents damages the transaction. This should be avoided. To seasoned corporate traders and bankers, using terms like "Letter of Intent" is the mark of amateurs. What you properly want is an RFQ, request for quotation, from a seller or supplier. The seller may then reply to your RFQ with a quote OR full offer if they wish.